CORRECTION: This story was updated on April 21, 2016, to clarify that the method described was not the first radical-based route to chiral quaternary carbon centers. The method is the first route ...
We decided to evaluate the use of alkenes as alkylmetal equivalents in catalytic asymmetric conjugate addition (ACA). These reactions would be strategically important because they would accomplish ...
The reaction utilizes an iron catalyst together with an N-heterocyclic carbene (NHC) ligand, which suppresses unwanted side reactions to promote highly selective nucleophile addition. In organic ...
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